It can be interpreted as the proportion of times we would be in a specific state if we let the Markov Chain run for a very long time.
Consider an irreducible Markov chain with a finite number of states. Then:
- the stationary distribution exists and is unique.
- $\pi_i = 1/r_i$, where $r_i$ is the expected amount of time it takes to return to state $i$.
Consider an irreducible and aperiodic Markov chain with a finite number of states (such a chain is usually called ergodic). Then any row of $Q^n$ is the unique stationary distribution, for $n$ large enough.